From Zagreb to Ulcinj in Montenegro there is a travel distance of about 800 km. This corresponds to a bus travel time of about 15-17 hours.
From Zagreb there are a few departures for which you can buy a ticket all the way to Ulcinj, the buses drive either via the Croatian highway or trough Bosnia.
You can see timetable for buses from Zagreb to Ulcinj here
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Map travel route Zagreb (HR) to Ulcinj (ME)
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